Last reviewed 16 Sept 2026 · 8 min read
Lime in construction
Lime was the principal binding material before Portland cement and remains useful in mortars, plasters, whitewash, soil stabilisation and restoration of heritage buildings.
Sources: limestone, chalk, kankar (impure nodular limestone), shells (sea shells), dolomite (for magnesian lime).
Terms
| Term | Meaning |
|---|---|
| Calcination | Heating limestone to a high temperature (around 900 °C) to drive off CO₂ |
| Quicklime (caustic lime) | Calcium oxide (CaO) obtained by calcination — white, amorphous, very reactive with water |
| Slaking | Chemical combination of quicklime with water, with heat, hissing and swelling |
| Slaked lime (hydrated lime) | Calcium hydroxide Ca(OH)₂ — a fine white powder |
| Milk of lime | Thin suspension of slaked lime in water — used for whitewash |
| Lime putty | Thick paste of slaked lime and water — for plaster and mortar |
| Setting | Hardening of lime — by carbonation (fat lime) or by hydration of silicates and aluminates (hydraulic lime) |
Chemistry of lime
Calcination:
Slaking (exothermic, volume increases):
Setting by carbonation (slow; needs air):
Hydraulic set: clay (silica and alumina) in limestone forms calcium silicates and aluminates on burning, which hydrate and harden like cement, even under water.
Molecular weights: CaCO₃ = 100, CaO = 56, CO₂ = 44, H₂O = 18, Ca(OH)₂ = 74.