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Controlled & Modified Atmosphere Storage

Respiration of harvested produce (climacteric and non-climacteric), respiratory quotient and Q10, ethylene production and action, ripening control (ethylene, 1-MCP, banned calcium carbide); controlled-atmosphere (CA) and ultra-low-oxygen storage — gas composition, equipment (gas-tight room, scrubbers, nitrogen generators, analysers); modified atmosphere packaging (MAP) — film permeability and equilibrium atmosphere with a worked example; hypobaric storage; commercial ripening chambers and applications in India.

📑 Contents (6 sections)

Last reviewed 1 Oct 2026 · 7 min read

Respiration of harvested produce

After harvest, fruits and vegetables continue to respire, using stored sugars and oxygen and releasing CO₂, water and heat:

Respiratory quotient (RQ) — about 1.0 for carbohydrate substrates, above 1 for organic acid oxidation, below 1 for fats (about 0.7), and rises sharply when fermentation (anaerobic) starts (CO₂ without O₂ use). Heat of respiration causes warming and is a major refrigeration load.

Rate and temperature (Q₁₀)

Worked ExampleExample — effect of temperature on respiration

A fruit has a respiration rate of 40 mg CO₂/kg·h at 20 °C, with .

  • At 10 °C: mg/kg·h.
  • At 0 °C: mg/kg·h.

Cooling from 20 °C to 0 °C reduces respiration by a factor of and thus roughly extends the storage life by a similar factor (other deterioration also slows).

Climacteric vs non-climacteric produce

Group Behaviour Examples
Climacteric A sharp rise in respiration and ethylene at ripening (climacteric peak); can ripen after harvest Apple, banana, mango, papaya, guava, tomato, avocado, pear, peach, plum, kiwifruit
Non-climacteric No peak; respiration falls slowly; ripen only on the plant Citrus, grape, pineapple, strawberry, cherry, watermelon, pomegranate, cucumber, capsicum

Ethylene

Ethylene (C₂H₄) is a gaseous plant hormone that triggers and speeds ripening, senescence, yellowing, sprouting and abscission; climacteric fruits produce much more (e.g., ripe apples, bananas, avocados). Effects: ripening, softening, loss of green colour (leafy vegetables), russet spotting (lettuce), off-flavour (bitter in carrot), sprouting; accelerates decay.

Control of ethylene:

Method Details
Ventilation Flushes the gas out
Ethylene scrubbers/absorbers Potassium permanganate (on alumina/zeolite) oxidises ethylene; catalytic oxidisers, ozone or UV photocatalysis
Low temperature and low O₂ (CA) Reduces production and action
1-MCP (1-methylcyclopropene) Blocks the ethylene receptors; used on apples and others (commercial, approved formulations)
Separate storage of ethylene producers and sensitive crops Basic rule

Ripening chambers

  • Controlled ripening of banana, mango, papaya, tomato by ethylene gas (about 100–150 ppm, from a cylinder or generator) at 18–20 °C and 85–95 % RH, for about 24 h, followed by ventilation to remove CO₂ and ethylene; banana ripening takes about 4–6 days with an appropriate temperature profile.
  • Ethephon (2-chloroethylphosphonic acid) releases ethylene when dissolved in water at the proper pH — used for fruit dips or sprays at regulated doses.
  • Calcium carbide (acetylene) for ripening is banned under FSSAI regulations in India — it is unsafe (it can contain traces of arsenic and phosphorus, damaging health). Approved alternatives are ethylene or ethephon in prescribed ways (check the current regulations).

This chapter is in the syllabus of

Open an exam to see where this chapter sits in its syllabus, and to practise it.