Last reviewed 16 Sept 2026 · 9 min read
Classification of engineering materials
| Group | Examples | Characteristics |
|---|---|---|
| Ferrous metals | Cast iron, wrought iron, carbon steels, alloy steels, stainless steel | Iron-based; strong, economical; most (except stainless) prone to corrosion |
| Non-ferrous metals | Aluminium, copper, zinc, lead, tin, titanium, nickel and their alloys | Corrosion resistance, conductivity, lightness (Al, Ti) |
| Polymers (plastics) | Thermoplastics (PVC, polyethylene), thermosets (epoxy, Bakelite), elastomers | Light, corrosion resistant, low strength and stiffness, temperature sensitive |
| Ceramics and glasses | Bricks, tiles, cement, glass, alumina | Hard, brittle, heat resistant, strong in compression |
| Composites | Reinforced concrete, FRP, plywood, fibre-reinforced cement | Combine properties of constituents |
Ferrous materials
| Material | Carbon content (approx.) | Properties / uses |
|---|---|---|
| Wrought iron | Very low (below about 0.1%) with slag | Ductile, malleable, corrosion resistant; largely obsolete |
| Low carbon (mild) steel | Up to about 0.25–0.3% | Ductile, weldable, tough — structural sections, reinforcement bars, sheets |
| Medium carbon steel | About 0.3–0.6% | Stronger — shafts, rails, gears |
| High carbon steel | About 0.6–1.5% | Hard — tools, springs, wires |
| Cast iron | About 2–4% (above the steel range of roughly 2%) | Brittle, strong in compression, good castability, damping — machine beds, pipes, manhole covers |
| Alloy steels | With Ni, Cr, Mo, V, Mn etc. | Improved strength, toughness, hardenability |
| Stainless steel | At least about 10.5% chromium (forms passive oxide film) | Corrosion resistant — kitchen equipment, cladding, chemical plants |
- Iron–carbon diagram: steel up to about 2.1% C; cast iron beyond (practical cast irons 2–4% C).
- Types of cast iron: grey (graphite flakes, machinable), white (hard, brittle), malleable, ductile (spheroidal graphite/nodular) — ductile iron pipes for water supply.
Non-ferrous alloys
| Alloy | Composition | Uses |
|---|---|---|
| Brass | Copper + zinc | Fittings, valves, taps |
| Bronze | Copper + tin | Bearings, bushes, statues |
| Duralumin | Aluminium + copper + magnesium + manganese | Aircraft structures |
| Gunmetal | Copper + tin + zinc | Valves, pump parts |
| Solder | Tin + lead (or lead-free alloys) | Joining |
Mechanical properties
| Property | Meaning |
|---|---|
| Strength | Ability to resist load without failure (tensile, compressive, shear) |
| Stiffness | Resistance to deformation — measured by modulus of elasticity |
| Elasticity | Ability to regain original shape after load removal |
| Plasticity | Ability to undergo permanent deformation without fracture |
| Ductility | Ability to be drawn into wires under tension (large elongation) — mild steel, copper, aluminium |
| Malleability | Ability to be hammered/rolled into sheets under compression — gold, lead, aluminium |
| Hardness | Resistance to indentation, scratching, wear |
| Toughness | Ability to absorb energy before fracture (area under stress–strain curve) |
| Resilience | Energy absorbed within elastic limit (modulus of resilience ) |
| Brittleness | Fracture with little deformation — cast iron, glass, concrete |
| Fatigue | Failure under repeated/fluctuating stresses below static strength; endurance limit |
| Creep | Slow time-dependent deformation under constant load, especially at high temperature |
| Machinability, weldability, castability | Manufacturing properties |
Stress–strain diagram of mild steel (tension test)
Key points:
- Proportional limit — end of linear (Hooke's law) region.
- Elastic limit — maximum stress without permanent set.
- Upper and lower yield points — sudden yielding (plastic flow) at nearly constant stress.
- Strain hardening region — stress rises with strain.
- Ultimate tensile strength — maximum stress; necking begins.
- Fracture (breaking) point — engineering stress appears lower due to reduced area.
- Percentage elongation and reduction in area measure ductility.
- Materials without a clear yield point (aluminium, high-strength steel) use 0.2% proof stress.
- Brittle materials (cast iron, concrete) fail with little plastic deformation.
Hooke's law and elastic constants
Stress ; strain Hooke's law: → elongation Poisson's ratio (steel ≈ 0.3; concrete ≈ 0.15–0.2) Shear: Relations: , and
Typical E: steel ≈ 200 GPa, aluminium ≈ 70 GPa, copper ≈ 110–120 GPa, concrete (M25) ≈ 25 GPa.
Hardness and impact tests
| Test | Method | Notes |
|---|---|---|
| Brinell (HB) | Hardened steel/tungsten carbide ball (commonly 10 mm) pressed with load (e.g. 3000 kgf); indentation diameter measured | ; suits softer/medium metals, castings |
| Rockwell (HRB, HRC …) | Depth of penetration by ball or diamond cone under minor and major loads | Quick, direct reading; widely used |
| Vickers (HV) | Square-based diamond pyramid (136°) | All materials, thin sections, microhardness |
| Mohs scale | Scratch hardness 1–10 | Minerals |
| Izod and Charpy impact tests | Pendulum strikes a notched specimen; energy absorbed measured | Toughness, ductile–brittle transition; Izod — cantilever specimen; Charpy — simply supported |
Heat treatment of steels
| Process | Procedure | Purpose |
|---|---|---|
| Annealing | Heat above critical temperature, slow furnace cooling | Soften, improve ductility and machinability, relieve stresses |
| Normalising | Heat above critical temperature, cool in still air | Refine grain structure, uniform properties (stronger than annealed) |
| Hardening | Heat above critical temperature, rapid quenching (water/oil) | Increase hardness (martensite) — but brittle |
| Tempering | Reheat hardened steel to a lower temperature, then cool | Reduce brittleness, relieve stresses, improve toughness |
| Case hardening (carburising, nitriding, cyaniding, induction/flame hardening) | Harden surface only | Hard wear-resistant surface with tough core — gears, cams |
Thermo-mechanically treated (TMT) bars used as reinforcement are produced by quenching the hot-rolled bar surface and self-tempering — giving a hard outer layer and ductile core.